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Natsu was able to defeat Zeref in what everyone assumes to be his Base, but if you notice beforehand Natsu's GuildMark began to glow before his final punch against zeref which gave him tons of power and the ability to negate Zeref's Power, so I believe that we should add a new form to Natsu's Page reffered to as Natsu Flames of Wild Emotion and make it High 6-C since he managed to defeat Fairy Heart Zeref with it