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For some reason people think that Natsu is the only one who can absorb fire, Ace can do the same. Both have Resistance to fire on a similar level so that won't be worth much. Ultimately it would come down to hand to hand in which I can see Ace having the advantage there since he can fight those with precog and enhanced senses without having either one of those two himself. He's also got way better stamina and endurance.