Yes, he did
There was the sound of sizzling, as though someone had thrown a burning torch into water. The spell which surpassed the very definition of tiers went off — and it looked as though the sun had risen on the land, dying everything in his field of view a brilliant white. The exothermic conflagration generated a rapidly-expanding wave of heat, which greedily consumed everything within its radius. This hell of a vision lasted only five seconds, but it felt dozens of times longer than that. Eventually, the brilliant white world disappeared. In the wake of the vanishing pulse of superhot energy was a large circular area — vastly different from before. Nothing outside the area of effect was affected. The trees were still trees, the earth was as full of vitality as the forest, and the forest itself was untouched — an extremely normal world. In contrast, the area within the circular area was charred black, converted into a dead zone of jaw-dropping proportions. The awe-inspiring temperatures had consumed all the vegetation in the area, leaving only a few carbonized tree stumps. There were several vitrified areas on the ground which were still emitting smoke. Standing beyond the bounds of that world which permitted no survivors, Ainz felt a dreadful presence washing out from within. It came from the only person who remained within that area. Nothing living could have survived that fatal heat. "Kakahaaah~ Kahaaaah~" That strange sound, accompanied by what seemed to be a gnashing of teeth, filtered into Ainz's ears. He turned to look at its source, and saw a point of red amidst a world scorched black. He saw Shalltear with wisps of smoke trailing off her body, and a look on her face which seemed to say, "not enough gun." Her crimson pupils, filled with hostility and bloodlust, focused on Ainz's body. "Ainz-samaaaa! That really hurt!"
Next
She was still flying back from the force of the explosion when Ainz hurled a black sphere after her. It was a spinning vortex of hyper-intensified gravity that could significantly damage a target, even one of Shalltear's level.
Then
As Ainz followed up with another spell, massive ribs erupted from the earth and closed in on Shalltear like a bear trap. The sharp points of white bone bit deeply into Shalltear's body.
