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Your argument has several flaws.Yeah, a rotted and corrupted Khemia creation of a Khaenriah-era Rhinedottir overpowers the Barbatos who was active during the Cataclysm - do with that info what you will /shrug
1: Not every Hexenzirkel is of equal strength, Mona is even a member. Are we going to start scaling Mona above the Archons?
2: Alchemy is basically the science of mixing stuff together. Khemia is just very advanced alchemy. There is no reason that should in any way be a UES.
3: Being very good at Khemia doesn’t mean that all of Rhinedottir’s stats suddenly scale. This would be like saying that a really good nuclear physicist is City Level.
4: Every Extant Archon save Makoto was stronger than Barbatos. Durin being stronger than Barbatos at best means it’s as strong as one of them.
So, even if all of what you are saying is true, the Hexenzirkel scale above two of the archons. The scaling chain isn’t broken by this.