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Given the fact that Luffy can only do somewhat substantial damage to Orochi via Ryou while in his giant form, I don't think his Precog will help him much here, as Orochi's horns would be like small but powerful pins hitting him. There's not much to dodge while in that form.But the problem here is Luffy has both really good precog and high unpredictability in this key, making hitting him much harder
Also, Orochi could very easily just surround Luffy with his dragons and horns with each of them having durability negation that would cut him up from the inside out.
Luffy is shown to still be weak to cutting attacks while in Gear 5th, which is practically Orochi's entire arsenal outside of heat attacks.
I'm voting Orochi due to Luffy not having any answer to his immortality, no answer to absorption (Orochi's raw AP would overpower Luffy's haki), no good answer to Orochi's danmaku of long ranged cutting shockwaves, shapeshifting, and technique copying.