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Hear me out on this one. Ussop and Nami were capable of percieving the movements of Baby 5 and Buffalo to tag them with their attacks. Not only that but in pre-time skip, Nami was capable of fighting and defeating Kalifa, as well as percieving and dodging her attacks, even if she wasn't as capable a fighter or on par with her. That should give her hypersonic reflexes right there, as well as Ussop who is known for being capable of sniping from several miles away from his targets, even if they are quite fast.