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Is there a context? Like a place where this happens for example? Do they have info on the other or are they unprepared?
I'd say Yubel should win because she has resistance to mind manipulation while Doom doesn't have resistance to some of his (yeah Yubel's not a girl in the original version) powers such as the multiple forms of mind manipulation, soul manipulation or reality warping. The only thing that makes me say "should" and not "will definitely win" is Doom's time travel device.
If doom was given time to prepare then i would say he stood a chance, but since there is no prep time, Yubel would win because like many other monster cards. She is more accustomed to fighting the instant she comes out. Or in this case she would be better off without prep time. Doom would need time to work out the kinks of Yubel and administer the correct device to defeat her.
Doom has a scan on his page for absorbing energy from Count Nefaria from the beginning of his fight, doing so to quickly reduce him to a powerless old man. Absorption that quickly renders 4-Bs powerless is too much for Yubel. Don't even need to get into the Tier 2 shit.