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He can win, he just has to actually get to Polnareff and land a killing blow, I just don't see him doing it against a character that outranges him, can't be smelled, can't be seen, can't touched or harm, can phase through every one of his attacks and attempts to conter, deflect and block on top of an extreme high probability of leading with shedding his armor like he did against Hol and Pol himself tending to try and kill his opponents right away unlike like Kak or Jotaro who try and incap first thus rending Tanjiro's overtime amps moot. Plus Pol can deal with fear aura, he'd still be effected but he can deal with it none the less to the point it won't prevent him from fighting.