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At the end of this video, we can see what happens. Impostor Bowser doesn't seem to be able to harm the Star-Powered Team, & after many blows, he's sent flying & ends up laying stomach down on the ground, as if knocked out.
Other footage in the video shows that when someone takes a hit in that mode from Impostor Bowser (When he's wandering. He doesn't seem to be able to do anything when they have Star Power.) , they get bubbled, & need someone else to free them.
I wonder if the same applies if a Chargin' Chuck hits someone in that mode?
There's also dialogue warning a player about "being targeted", so that's interesting, too.