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He should because of scaling that isn't necessarily legit. If Doffy used Haki to break free of the ice then Luffy could scale, but there's no evidence.
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There's a massive difference between -270 degrees celsius or -454 fahrenheit and "really cold." I don't think Luffy has a feat of resisting something that cold.Schnee One said:Nigh Absolute Zero is still an extremely cold temperature