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Pikachu's other Z-Moves don't have 4-B scaling outside of contributing half the power to overpower a Guzzlord. Its 10,000,000 Volt Thunderbolt is consistently depicted as vastly superior to Gigavolt Havoc and is treated as a massive upgrade to it in-universe, at least as far as I can tell.ProfessorKukui4Life said:Just because somethings done a lot doesn't mean its not an outlier.
For Pikachu's Z-Moves to be considered 4-B, you would have to make an argument for Z-moves in general being 4-B. And we also don't accept that as far as im aware.
I think at least High 7-A, likely higher is most reasonable. We can confirm Pikachu is at least high-end High 7-A and can make an at least 6-B flinch from a Thunderbolt, so it's definitely reasonable to say it's likely higher than High 7-A.
As for its other scaling, I think the best we can do is just making Pikachu 4-B with 10,000,000 Volt Thunderbolt, seeing as it one-shot Guardian of Alola and Nihilego with it. There is argument for Pikachu to be 4-B with other Z-Moves such as Gigavolt Havoc but I honestly think that topic, in itself, should be separated from upgrading to at least High 7-A and 4-B with 10,000,000 Volt Thunderbolt.