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Spiderman shoots a dozen or so webs and restrains her easily

This is basically Spiderman vs Winter Soldier and Falcon only now it's one at a time and he's not getting caught off guard
 
I think Bucky kinda sorta scales to Cap who scales to Spidey who is 329 megajoules

Also Bucky wins.

Bucky's arm is the main deciding factor here as it is significantly higher than his base AP which is comparable to Nebula and if he blocks with his arm Nebula ain't scratching that.

Voting Bucky
 
Bucky FRA, not much else I can add.

Despite Nebula's more ehnhanced body. Bucky is more then skilled enough to keep up and the arm gives him the win
 
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