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Her mind resistance is enough to shrug off that of the teigu when she first acquired it, a simple taste is enough to make someone insane, but the whole grail got nulled, so Ice Lock is out of the question.
Big reason, Invel AP wise is baseline 7A, Esdeath herself, casually one shotted a Baseline 7A, so she's going in with a very good AP advantage.
His Ice resistance can probably shrug off Mahapadma, but it won't stop her other Ice attacks from hurting him. Plus if all goes south, she can go close and tear him up with her rapier, which ultimately beats his fists weaponry wise
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Invel mind ability more like control body well i dont really know how his power work.
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Same with natsu casual one ahot 7A or 6C still get freez before he can do anything.
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At this she might already got freez.