Breaking it down further, I want to bring up specific concerns coming from a professional star wars wanker.
One. How likely will bayonetta open with not only time stop, but also time travel, kill luke as a baby and call it a day?
Two. How likely will she use bazillions in a fight and right away before luke can counter? (spoiler, very likely)
Etc etc. We can go with this line of reasoning forever since this is practically who hits first, but we should ask who will likely hit first.
Which in that case..
Luke Advantages -Precognition
-Clairvoyance
-Psychometry
-Higher AP
-Force Stun
-Mind Hax Bayonetta Advantages
-Molecular Destruction via Bazillions
-Invulnerability and Healing with Lolipops
-Time Hax and Teleportation (Luke doesnt get fold space until after his fight with Abeloth I believe)
-Attack Reflection and BFR.
-More Combat Experience
Pretty much I think personally, if we saw the two walk up to eachother, we know three things.
One: Luke will likely know what to do and what not to do. Two: Bayonetta, assuming in character, would likely open up with one the of the above hax. Three: The two combined will have to analyze eachothers battle plans.
This will be either be a long battle or a short one... But I change my vote to Luke. Not because I dont believe Bayonetta wouldnt open up with hax, but more so just based on their abilities. Yes Bayonetta is far more versatile and has more experience. But Luke's combination of abilities should be enough to pull through a win. He just 'knows' that mind hax will work and he can use them. Or he can slice off Bayo's head, or use precog to see a time stop and instantly use mind hax to stop it.
No matter how you frame it, Luke is more likely to be able to hit first then second. There is worlds where Bayonetta wins by getting bazillions out first or maybe time stop is likely.
It is just that imo, Luke is far more likely to win vis Precog, Clairvoyance, Psychometry, and Mind Hax.)
And to counter the argument 'But bayo can also oneshot so inconclusive!"
Yeah. But I am also 89 percent sure Bayonetta does not have precognition.
And Lukes precog is actually fairly powerful, allowing him to see hours into the future outside of combat and minutes in it.
Luke via precog, clairvoyance, psychometry, higher ap and mind hax.
Sorry my favorite waifu, better luck next time. <\3