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The wiki concluded that Base Gohan scales to 6 Universes because he vaguely scales to a suppressed Gamma 1 who Piccolo said was vaguely comparable to Goku.I once did Golden Frieza (Broly Saga) vs Ultimate Gohan (Super Heroes) and it was declared a stomp in Gohan's favor. Perhaps SSJ Gohan vs Golden Frieza?
So it's something like:
SS1 Gohan (SH) > (50x) > Base Gohan (SH) ~ Gamma 1 (Suppressed) ~ Goku Blue (SH, Hypothetical) > (2 years training) > Goku Blue (Broly) > Goku Blue (Post-UIS2) > UIS1 Goku = 6 2-C
For Golden Freeza it's:
SS1 Broly > (50x) > Wrathful Broly ~ Goku Blue (Broly) > Goku Blue (Post-UIS2) > UIS1 Goku = 6 2-C
Which puts Golden Freeza somewhere between SS1 and Wrathful. Suffice to say the scaling chain for Gohan is too large for Freeza.
Even if I presume Piccolo didn't see Goku since the Broly movie:
SS1 Gohan (SH) > (50x) > Base Gohan (SH) ~ Gamma 1 (Suppressed) ~ Goku Blue (Broly) > Goku Blue (Post-UIS2) > UIS1 Goku = 6 2-C
So you could argue SS1 Gohan (SH) is equivalent to SS1 Broly (Broly) because Base Gohan is scaled to Suppressed Gamma 2, when suppressed Gamma 2 was compared to Goku by Piccolo. Meaning SS1 Gohan would stomp Freeza like how Broly stomped him.
And no, Base Gohan wouldn't work. Because he should get stomped by Golden Freeza based on the scaling chains and where EXACTLY Base Gohan scales is a bit unclear anyways.
tl;dr
I don't think there are any good matchup choices here because Gohan's scaling is a mess to understand and Gohan either stomps or is stomped depending on the form used. The only 'Gohan vs Freeza' matchup that even remotely works scaling-wise is from the ToP. It's the only time they're explicitly comparable.