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Tensei Shitara Slime Datta Ken (LN) gets an upgrade though this change only affects 3 character profiles currently due to the WN/LN seperation (though the others should get their LN profiles sooner or later too). This Tier upgrade does not affect the Web Novel version in any way. Before the WN/LN split happened (and even now) most characters were stuck at the same Low 7-B AP despite obvious differences in power, all due to a lack of concrete feats. Now there it seems that the AP range can be widened a bit.
So the storm pic here shows the attack called "Death Storm" by Ranga. When Ranga still had a WN/LN composite profile, a calc was appearently done, which resulted in this AoE attack to be rated as High 7-A, according to Celestial Pegasus, but it seemed to be an attack that could only be used a single time before running out of magical energy and it was a dispersed AoE attack against red-shirt Orcs, so it was only kept as a seperate attack.
Now however there is more concrete proof of a High 7-A feat from the "Veldora's Slime Observation Journal": Orc Disaster Geld managed to tank a High 7-A attack that has been concentrated on a single target and that was only after already tanking a barrage of other attacks. It's the same Death Storm attack, just a "pin-pointed" single-target version of it, hence it's a feat of withstanding a High 7-A attack. It should be noted that Orc Disaster Geld doesn't have any known resistance against electricity or lightning either, so its not due to a hax or anything like that. In addition, this also proves that Ranga was able to use that attack twice rather than once.
How should characters scale based on that? I don't know. The reasoning for the keys in the WN is not valid in the LN version anymore. So I'd like your input on this.
If High 7-A is the current maximum, then Low 7-C would be the current minimum, at least for A ranks, since the lowest known requirement to be rated "A-Rank" seems to be the capability to destroy a small tow. Though I'd like your input on that as well since it's not specified concretly whether or not that requirement includes characters and monsters with "A-Minus" rank.
Now for the new keys, let's keep them down at 1 for Rimuru for now, unless there is some major reason given to divide it into seperate keys, since the release for LN vol. 5 is not far off. Charybdis being only 1 key is a given. Shizue should still be divided into "current" and "peak" keys, since her role is pretty much finished in the story, at most there will be some revisions, but likely no new content in regards to her.
Now for my personal estimations:
Charybdis should completely scale up to High 7-A, but not sure about whether or not it deserves a further "at least High 7-A" attached to it. While it has immense energy reserves and durability it couldn't manage to kill even a single fodder among the Tempest-Dwargon alliance that attacked it.
Rimuru should scale up to either High 7-A or 7-A before eating Geld, but definitly High 7-A afterwards. That is because compared to Ifrit, a "Special A Rank" Calamity-Threat, Orc Disaster Geld got twice the mount of magical energy, which makes him a Special A too. On the other hand Rimuru also got a higher amount of magical energy compared to Ifrit, though it's not specified by how much, but Orc Disaster Geld has less than twice of Rimuru's energy, so Rimuru is a safe lock for 7-A tier at the minimum even before eating Geld and pretty much guaranteed for High 7-A afterwards. Though since Rimuru is superior to Ranga, he might be High 7-A even before that. I am not sure. Tell me what you think.
Shizue, I have no idea how to evaluate her, maybe we could seperate her tiers between "base" and "when using Ifrit". I can't help but think that considering how she was unable to even damage a Dragon without Ifrit being unleashed at the end of her peak period. With Ifrit it'd scale to 7-A though for the same reason as Rimuru.