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Some Holy Magicules use spirit particles as their power source. Holy attacks all follow the premise of "purifying" magicules and operate upon faith. Spiritual attacks (at least those that utilize spirit particles) do not operate this way. Faith isn't a factor and it doesn't have the purification effect. But since they can overlap people tend to be confused and treat them similarly.I interpreted it as there is no space in between Rimuru and the rest of the world, like it's been ripped. So conventional attacks might not work against it since attacks have no space to travel to. Holy Manipulation users work since they can bypass space-time barrier altogether. Could be wrong though, that's just how I understood it.
I remember comparisons between Absolute Defense and Infinite Prison's barrier, but can't access quotes as of now so ignore this for now.