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Actually, yes she does "passively" paralyze her opponent the moment she enters Undying, as shown in the Genocide Route. From the start of the battle, you're instantly in Green Mode and have to defend yourself with the spear Undyne gives you (I don't have an ounce of a clue as to why she would, but we'll overlook that). Her Danmaku is, to say the least, one of the trickier ones to evade in Undertale, especially once reverse spears get thrown into the equation. Even in the best of circumstances, Doomguy wouldn't be expecting flurries upon flurries of spears to be making a beeline towards him all at once, nor would he expect the reverse spears.