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I can't say I know Iron Man, MCU, very well, but I'd say it's probably going to Iron Man. Though, it could go to Weiss, seeing as her partial summon during the season 3 final crushed a damaged mech. Coupled with dust, she might have a chance.
Written with only a quick glance at each character's profiles, and vague recollections of the Iron man movies, and RWBY*
Going to have to agree with Gemmy, Stark has Friday, which as we have seen in Civil War,
*Spoilers*
was able to analyse and counter Captain America's fighting technique. This coupled with an ever-changing armour and overwhelming firepower, I'd say Iron Man wins.
Iron Man wins. Hulkbuster is way too much for her and even if she managed to damage it it'll just replace its parts.
If not that, Iron Man's overpowered analytical skills will just figure out her fighting style. If not that, then, well, I don't think Weiss can tank a laser that slices clean through steel.