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Am I illiterate? The timeframe is 1 second based on it immediately reaching him, not based on Stark's reaction timeframe, right?
"When Stark noticed something and he tried to block Freeren, the arrow immediately reached him. I will spend 1 second for this achievement."
The "happened instantly" is based on Stark's reaction. We don't actually know when it was fired to when it struck. The assassin also points out there was a big gap between him and Stark, which would give Stark a bit extra time to react. (Like for example, even you could dodge a bullet at 1km away).
1 second is based on Stark's reactions.
As an fyi though, isn't her mana sensing 20km, not 10km? Would double the feat.