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Was that explosion anywhere near as large as the one shown in the DCAU? Because that thing was at least three times the size of the initial island after the burst. Said explosion also obliterated the Volcano, either way Superman and Doomsday should get a huge upgrade.It is, because you're using the entire size of the island to get a size which then gets you KE figures that gets a big number.
Most volcanic eruptions don't give nearly that level of thermal energy. St. Helens for example had the following
Even giant island shatter explosions like Krakatoa only generated 200 megatons of TNT
Eruptions just do not generate the level of energy you're suggesting they do.