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Not sure, Venusaur has longevity in that he can heal and even cause damage and heal with leech seed and drain moves but Satsuki has flight and ranged attacks so she could keep a distance and attack out of reach but he can just keep healing, if she stays close she'd lose via damaging healing moves and being bounded with vines and not being able to retaliate but at a range she may take it with flight and ranged attacks.
I'd say Venusaur because Poison Powder, Sleep Powder, Leech Seed can sap off Satsuki's strength while Razor Leaf and Vine Whip maintain the distance. Venusaur essentially just needs to stay out of Satsuki's range while Poison, Sleep and Energy Drain do the rest. She may be able to cut off the Leech Seed, but Powder moves, not so lucky