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Peter has various ways on containing/sustaining Raiden via his webshooters, Electric Web, even gravity manipulation with suspension matrix. He has precognition so that might be useful against Raiden's HF Blade which is required to be within several meters

He also has a big AP advantage, being 5x that of Raiden

However...Raiden can just stun grenade his kit, out skill him and one shot him with the HF blade, so I'll vote for Raiden