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Doofenshmirtz is capable of doing anything he wants if enraged enough, such as being attacked. And Doofenshmirtz is, in fact, very very smart, he just isn't that good at putting 2 and 2 together.
Doof is a very intelligent individual whose created incredibly advanced and powerful machines, no arguing there. The main difference is attitude, though. Rick is a cold hearted individual whose willing to murder without a second thought, while Doof, well, doesn't. I think Rick would just kill Doof before Doof can fight back.
Give them both bloodlust and you'll have a VERY even match, actually.
Otherwise Rick would yawn and blast him before he even gets a chance to bring up his evil scheme.
I honestly want to see this as a Death Battle. 3-D animated with voice acting and everything. They'd be able to make a scenario around it and everything. Even though the outcome would be obvious, it'd be extremely entertaining.