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I vote Lucario
The reason is that Lucario is more experienced in combat and has a bigger variety of physical and ranged attacks, in addition to many ways to boost his statistics and lower those of All Might. It can also sense All Might's presence and read his mind.
Lucario is weaker in terms of pure AP (326 megatons vs 438 megatons), even though the gap might be closer or not, depending on if you want to upscale them from the characters/feat they already scale and to what extension. You can also argue that All Might's punches deal more damage to Lucario due to its weaknesses to fighting type. But, overall, that doesn't really matter, due to reasons above, Lucario has an edge in versatily and ability that should grant it the victory.
P:S: I didn't take in accounts elements and feats from Mystery Dungeon, since they aren't considered canon anymore and wouldn't change the verdict