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Warning: I am looking at this from a Competitive Point-of-View.
So feel free to ignore this should it suit you. I just wanted to get my two cents out there.
That being said, Emboar takes this for having more OHKO options then Infernape. Infernape is too frail to take more then one hit, so it needs to OHKO Emboar, and it's only real option is Tectonic Rage. Emboar on the other hand has that, plus Hydro Vortex and Shattered Psyche. Emboar's standard Earthquake also OHKOs Infernape, where as Infernape's Earthquake only 2HKOs. That allows Emboar to wear a Choice Scarf, which allows it to now outspeed Groundium Infernape too. On top of that, both STAB Superpower and Reckless-boosted Head Smash have a small chance to OHKO Infernape.