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I understand how the The World part attaches to DIO. But where does ST fit in that name? Anyway, depends on at what point in the series DIO is at. If it's during part 3 but before DIO's World, then DIO dosn't know what a car is.
If he knows what a car is at the time he just stops time and kills Sweet Tooth. If he dosn't he'll think that Sweet Tooth (The car) is a stand. IDK what would happen then.
DIO knows what an automobile is, he demonstrates his knowledge about it during their car chase.
He's been alive for a year at that point and he spent most of his time reading books. DIO isn't behind on technological advancements since Phantom Blood.