I'm not sure if Carnivores can compete with GTA in terms of weapon variety though... (not to mention vehicles)
Both turn out to have very powerful weapons though.
Also, not sure if game mods should be accounted for... welp (if not, ignore the mods page
The following is a list of weapons that can be used in Grand Theft Auto: San Andreas. Grand Theft Auto: San Andreas features 38 different weapons and three special items, where they follow the same mechanics as in previous titles, however, the arsenal has been expanded with the introduction of...
gta.fandom.com
The following is a list of vehicles that can be controlled in Grand Theft Auto: San Andreas. There is a total of 192 vehicles. Vehicle Stats in GTA San Andreas Mod shops in Grand Theft Auto: San Andreas: Loco Low Co. TransFender Wheel Arch Angels
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carnivores.fandom.com
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If we're going by default equipment usage as listed in profiles... if the radar/map and other location finding tools for the Hunter can also detect human targets, the Hunter is more likely to have the element of limited preparation and surprise, but the Hunter will also need to ensure that he can either bypass or negate Big Smoke's durability (landing headshots or shooting other unarmoured parts of the body)... I'm not sure if the Hunter himself has any form of armour welp.
I feel like the Hunter should take this based on bigger variety of equipment as compared to Big Smoke as shown in their profiles...
So my vote is on Hunter winning.