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Alex would probably start with his Information Analysis before attacking with his sword or using his magic attacks (The magic skills he can use is his 9-A key are his Support Skill, Fire Flash, Blazing Strike, Fire Flash Full Power, Incineration slash, Fire Fist and Outburst Wave). What do Spider-Man and Black Widow start with and how would they react to Alex's magic?
Spider-Man has precog to help him dodge attacks. He usually uses webbing to stop characters from attacking and help him beat up the opponent. Black Widow uses invisibility to go in for a surprise attack, if that fails, its guns and H2H combat.
While Alex has the AP advantage, I see this fight becoming a long drawn out fight, mostly thanks to Spidey's Precog. Widow definitely will be best suited in the support role once she realises that going up H2H is a bad idea. Both Widow's and Spidey's Stat reduction will be useful slowing him down, worsening his accuracy, and AP, enough to allow there own stat amping to get reasonably closer.
Alex does have the better stamina, but ISO-8 helps slowly keep Spidey and Widow in the game and it's too difficult, for me at least, to determine a clear winner.