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Shouto more so has high temperature resistance but he’s probably just as susceptible to getting stabbed with ice as anyone else in his verseShouto resists ice and that's Emilia's entire arsenal really.
If her ice does work on him then she one-shots. Since Shoto only has 8-C dura.
AP is 328 tons for Emilia to 194 for Shoto
Edit: Actually, I'm pretty sure Emilia wins since iirc Shoto's body can't take too much cold, right? His resistance doesn't seem very great. And her attacks can withstand fire so, it's only going to be so long before he gets one-shot by a danmaku of ice attacks.